NIST Structural Ceramics Database (SCD)

Bibliographic Information
SCD Citation Number: Z00363

Reference:
"Reliable Ceramics for Advanced Heat Engines," V.K. Pujari, D.M. Tracey, M.F. Foley, N.I. Paille, P.J. Pelletier, L.C. Sales, C.A. Willkens, and R.L. Yeckley, American Ceramic Society Bulletin, Vol. 74 [4], pp. 86-90 (1995), published by American Ceramic Society.
Language: English



General Materials Processing Notes
SCD Citation Number: Z00363

"The material produced is designated NCX-5102 and consists of a silicon nitride-4% yttria composition that is densified by glass-encapsulation HIPing. ... Large-scale batches (30 kg) of Si3N4-4% Y2O3 powder were milled in water, and the slurry was used to cast hundreds of tensile rods. The starting Si3N4 powder (Ube) was derived from a dimmide process. ... The net-shape-formed bars were HIPed using glass encapsulation (ASEA Cerma AB, Robertsford, Sweden). The HIP process was optimized using pressure, time and temperatures to assure full densification and development of an elongated microstructure for desired fracture toughness..."



Index of Materials and Properties
SCD Citation Number: Z00363


Measurement Methods
SCD Citation Number: Z00363


Literature survey
The authors cite V.R. Pujari et al., "Development of Improved Processing and Evaluation Methods for High Reliability Structural Ceramics for Advanced Heat Engine Applications, Phase I," final report, ORNL/Sub/89-SB182/1, NTIS Rept. No. DE93-040528, August (1993), and summarize the procedure as follows. "The cylindrical buttonhead specimens were machined to ORNL design with a gauge diameter of 6.0±0.1 mm. ...50 mm diameter, 150 mm long specimens... were machined as many flexure bars (3 mm by 4 mm by 50 mm) for assessment of the properties across the 50 mm section."
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Material Specification and Properties for Si3N4·x Y2O3
Material number 1 of 1
in SCD Citation Number: Z00363

Chemical Class: Nitride
Chemical Family: Si-N:Y2O3
Formula: Si3N4·x Y2O3
Informal Name: silicon nitride composite
Structure Type: Polycrystalline
Manufacturer: Saint-Gobain/Norton Industrial Ceramics
Commercial Name: NCX-5102
Process: Hot Isostatic Pressing




Si3N4·x Y2O3
Material number 1 of 1
in SCD Citation Number: Z00363

Elemental Composition
Amount of
Element
( formula units )
Element
 
( no unit )
3 Si
4 N


Measurement Method: Reported Formula
Evaluation Status: Unevaluated



Si3N4·x Y2O3
Material number 1 of 1
in SCD Citation Number: Z00363

Sintering Aids
Sintering Aid
Mass Fraction
( % )
Sintering Aid
 
( no unit )
4 Y2O3


Measurement Method: Reported Formula
Evaluation Status: Unevaluated



Si3N4·x Y2O3
Material number 1 of 1
in SCD Citation Number: Z00363

Flexural Strength
Test
Temperature
( °C )
Flexural
Strength
( MPa )
23 972
1370 561


Measurement Method:
Literature survey
Evaluation Status: Evaluated by acceptance criteria
Cautions:
"The nonlinear character of the distribution with multiple inflections suggests that a two-parameter Weibull fit of these data (0 = 1038 MPa, m = 10.4) is inappropriate and that the multimodal nature of the data should be represented using competing risk analysis. ... The important feature of the three-parameter Weibull distribution is the existence of a threshold stress below which there is zero proability of failure."


Si3N4·x Y2O3
Material number 1 of 1
in SCD Citation Number: Z00363

Tensile Strength
Range of
Strengths
( MPa )
Test
Temperature
( °C )
Tensile
Strength
( MPa )
540-1237 23 997
344-452 1370 396


Measurement Method:
Literature survey
Evaluation Status: Evaluated by acceptance criteria
Cautions:
"The nonlinear character of the distribution with multiple inflections suggests that a two-parameter Weibull fit of these data (0 = 1038 MPa, m = 10.4) is inappropriate and that the multimodal nature of the data should be represented using competing risk analysis. The important feature of the three-parameter Weibull distribution is the existence of a threshold stress below which there is zero probability of failure."


Si3N4·x Y2O3
Material number 1 of 1
in SCD Citation Number: Z00363

Weibull Modulus
Weibull
Strength
( MPa )
Threshold
Strength
( MPa )
Test
Temperature
( °C )
Stress
Mode
 
Weibull
Modulus
( no unit )
1109 665 23 Tensile 4
--- 653 23 Flexural ---
--- 517 1370 Flexural ---


Measurement Method:
Literature survey
Evaluation Status: Evaluated by acceptance criteria
Cautions:
"The nonlinear character of the distribution with multiple inflections suggest that a two-parameter Weibull fit of these data (0 = 1038 MPa, m = 10.4) is appropriate and that the multimodal nature of the data should be represented using competing risk analysis. The important feature of the three-parameter Weibull distribution is the existence of a threshold stress below which there is zero probability of failure."


Si3N4·x Y2O3
Material number 1 of 1
in SCD Citation Number: Z00363

Weibull Strength
Threshold
Strength
( MPa )
Weibull
Modulus
 
Test
Temperature
( °C )
Stress
Mode
 
Weibull
Strength
( MPa )
665 4 23 Tensile 1109


Measurement Method:
Literature survey
Evaluation Status: Evaluated by acceptance criteria
Cautions:
"The nonlinear character of the distribution with multiple inflections suggests that a two-parameter Weibull fit of these data (0 = 1038 MPa, m = 10.4) is inappropriate and that the multimodal nature of the data should be represented using competing risk analysis. The important feature of the three-parameter Weibull distribution is the existence of a threshold stress below which there is zero probability of failure."
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SCD date of first release: October 1990.
SCD date of last update: 3 January 2002.

Date page created: 3 January 2002.

Page last updated: 3 January 2002.


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